Selective hydrogenation of 1,3-butadiene in presence of 1-butene under liquid phase conditions with NiPd/Al2O3 catalysts

The catalytic performance of Al2O3-supportedmonometallic and bimetallic catalysts in selective hydro-genation of 1,3-butadiene in the presence of 1-butene underliquid phase conditions was studied. Bimetallic catalystswere prepared by the coimpregnation method with therequired amounts of the precurso...

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第一著者: F.J., Méndez (author)
その他の著者: Solano, Roger (author), Villasana, Yanet (author), Curbelo Susana (author), Inojosa Marcel (author), Olivera Fuentes Claudio (author), Brito, Joaquín L. (author)
フォーマット: article
出版事項: 2016
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オンライン・アクセス:http://repositorio.ikiam.edu.ec/jspui/handle/RD_IKIAM/300
https://doi.org/10.1007/s13203-016-0149-y
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要約:The catalytic performance of Al2O3-supportedmonometallic and bimetallic catalysts in selective hydro-genation of 1,3-butadiene in the presence of 1-butene underliquid phase conditions was studied. Bimetallic catalystswere prepared by the coimpregnation method with therequired amounts of the precursors salts [Ni(NO3)2 6H2Oand Pd(NH3)4Cl2 H2O] over pellet-formc-Al2O3with aconstant content of Pd (0.5 wt%) and varying Ni/Pd atomicratio (0.25, 0.5, 0.75, and 1) obtainingegg-shellprofiles ofthe active components. The catalysts were characterized byX-ray diffraction, temperature-programmed techniques,such as reduction in hydrogen and desorption of ammonia,N2physisorption, and transmission electron microscopy.The catalytic test showed that the 1,3-butadiene wasselectively hydrogenated when bimetallic catalysts wereused. The addition of Ni to the Pd-based catalysts sup-pressedn-butane formation and increased recovery of1-butene at medium conversion. Therefore, it was observedan improved catalytic performance of the bimetallic cata-lysts being highest in the case of the 1NiPd/Al2O3.