The flexible surface revisited: Adsorbate-induced reconstruction, homocoupling, and sonogashira cross-coupling on the Au(100) surface

Phenylacetylene (PA) and iodobenzene (IB) are prototypical reactants in Sonogashira cross-coupling. Their adsorption behavior and reactivity on the Au(100) surface were studied by STM, temperature-programmed desorption and reaction, and DFT calculations that included the effect of dispersion forces....

• מחבר ראשי: Feria Hernandez, L. (author)
• פורמט: article
• יצא לאור: 2017
• נושאים: acetylene; adsorption; chemical reactions; temperature programmed desorption adsorption behavior; adsorption energies; close packed structures; different substrates; dispersion force; flexible surfaces; roughened surfaces; sonogashira cross; coupling
• גישה מקוונת: http://dx.doi.org/10.1021/jp501321u; http://dspace.utpl.edu.ec/handle/123456789/19113